C.P.A. Logo   Welcome to cpachem.com
  Classical analytical methods ...
ALUMINIUM
    gravimetry
    volumetry

AMMONIUM
    gravimetry

ANTIMONY
    gravimetry
    volumetry (oxidimetry with iodate with bromate

ARSENIC
    gravimetry
    volumetry ( iodometry ; precipitation titration via silver arsenate ; oxidimetry )

BARIUM
    gravimetry

BERYLLIUM
    gravimetry

BISMUTH
    gravimetry

CADMIUM
    gravimetry

CALCIUM
    gravimetry ( as oxalate ; as carbonate ; as oxide )

CERIUM
    gravimetry

CHLORATE
    gravimetry
    volumetry ( iodometry ; redoximetry )

CHLORIDE
    gravimetry

CHLORINE
    volumetry

CHROMIUM
    gravimetry
    volumetry

COBALT
    gravimetry

COPPER
    gravimetry
    volumetry

CYANIDES
    gravimetry
    volumetry

GOLD
    gravimetry

 HEXACYANOFERRATES(III)
    volumetry

HYDRAZINE
    volumetry

HYDROGEN PEROXIDE
    volumetry

HYDROXYLAMINE
    volumetry

IRON
    gravimetry

LEAD
    gravimetry

LITHIUM
    gravimetry

MAGNESIUM
    gravimetry

MANGANESE
    gravimetry

MERCURY
    gravimetry

MOLYBDENUM
    gravimetry
    volumetry

NICKEL
    gravimetry

NITRITE
    volumetry

OXYGEN
    dissolved
    COD (Chemical Oxigen Demand)

PALLADIUM
    gravimetry

PERSULPHATES
    volumetry

PHENOL
    volumetry

PLATINUM
    gravimetry

POTASSIUM
    gravimetry
    volumetry

SELENIUM
    gravimetry

SILVER
    gravimetry

SODIUM
    gravimetry

STRONTIUM
    gravimetry

SULPHIDE
    volumetry

SULPHITES
    volumetry

THALLIUM
    gravimetry

THORIUM
    gravimetry

TIN
    gravimetry

TITANIUM
    gravimetry

TUNGSTEN
    gravimetry

URANIUM
    gravimetry

VANADIUM
    gravimetry

ZINC
    gravimetry

ZIRCONIUM
    gravimetry

 
  Determination of elements by Instrumental Analysis ...
ALUMINIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
ANTIMONY
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
ARSENIC
    by AAS-GTA
    by ICP-AES
BARIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
BERYLLIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
BISMUTH
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
Boron
    by AAS-GTA
    by ICP-AES
CADMIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
CALCIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
CERIUM
    by ICP-AES
Cesium
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
CHROMIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
COBALT
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
COPPER
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
Gallium
    by AAS-GTA
    by ICP-AES
germanium
    by ICP-AES
GOLD
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
hafnium
    by ICP-AES
indium
    by AAS-GTA
    by ICP-AES
iridium
    by ICP-AES
IRON
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
LEAD
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
LITHIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
MAGNESIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
MANGANESE
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
MERCURY
    by AAS-Flame
    by ICP-AES
MOLYBDENUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
NICKEL
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
niobium
    by ICP-AES
osmium
    by ICP-AES
PALLADIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
Phosphorus
    by AAS-GTA
    by ICP-AES
PLATINUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
POTASSIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
Rare earth elements
    by ICP-AES
rhenium
    by ICP-AES
rhodium
    by ICP-AES
rubidium
    by AAS-GTA
    by ICP-AES
ruthenium
    by ICP-AES
scandium
    by ICP-AES
SELENIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
SILICON
    by AAS-GTA
    by ICP-AES
SILVER
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
SODIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
STRONTIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
Suphur
    by ICP-AES
Tantalum
    by ICP-AES
Tellurium
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
THALLIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
THORIUM
    by ICP-AES
TIN
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
TITANIUM
    by AAS-GTA
    by ICP-AES
TUNGSTEN
    by ICP-AES
URANIUM
    by ICP-AES
VANADIUM
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
yttrium
    by ICP-AES
ZINC
    by AAS-Flame
    by AAS-GTA
    by ICP-AES
ZIRCONIUM
    by ICP-AES
 
  C.P.A. - Frequently asked questions about chemical standard solutions ...

Q: What is custom-made solution?

A:

Custom-made (tailor-made or ready-to-use) solution is a solution (single or multi-element) prepared according your specific needs and requirements: analytes, analysis, matrixes, concentrations. Custom-made solution is a product, with a real practical application compared to the conventional standard solutions (element standard or multi-element standard). Instead of gathering 2 or more conventional solutions you simply order one you need. You will achieve correct results without any interference of the other components: matrix, type and concentration of analytes. Furthermore you will avoid any errors due to preparing, precipitation mixing of incompatible solutions, calculations, contamination etc

Q: What is ICP-AES?

A:

ICP-AES is short for optical emission spectrometry with inductively coupled plasma. The plasma is formed by argon gas flowing through a radiofrequency field where it is kept in a state of partial ionisation, i.e. the gas consists partly of electrically charged particles. This allows it to reach very high temperatures of up to approx. 10,000ºC. At high temperature, most elements emit light of characteristic wavelengths which can be measured and used to determine the concentration.

The sample being analysed is introduced into the plasma as a fine droplet aerosol. Light from the different elements is separated into different wavelengths by means of a grating and is captured by light-sensitive detectors. This permits simultaneous analysis of up to 80 elements and ICP-AES is consequently a multi-element technique. In terms of sensitivity, ICP-AES is generally comparable to flame atomic absorption, i.e. detection limits are typically at the µg/L level in aqueous solutions.

C.P.A. provides single-element (mono-element) ; multi-element standard solutions and custom-made solutions for ICP-AES.

Q: What is AAS; FAAS?

A:

Atomic absorption spectroscopy (AAS; AAS-Flame) determines the presence of metals in liquid samples. Metals include Fe, Cu, Al, Pb, Ca, Zn, Cd and many more. It also measures the concentrations of metals in the samples. Typical concentrations range in the low mg/L range.

In their elemental form, metals will absorb ultraviolet light when they are excited by heat. Each metal has a characteristic wavelength that will be absorbed. The AAS instrument looks for a particular metal by focusing a beam of uv light at a specific wavelength through a flame and into a detector. The sample of interest is aspirated into the flame. If that metal is present in the sample, it will absorb some of the light, thus reducing its intensity. The instrument measures the change in intensity. A computer data system converts the change in intensity into an absorbance.

As concentration goes up, absorbance goes up. The researcher can construct a calibration curve by running standards of various concentrations on the AAS and observing the absorbances. C.P.A. provides standards, and ready-to-use calibration sets of standards of various concentrations for AAS. Tailor-made mono-element (single-element) and multi-element solutions are also avaible.

Q: What is ETAAS? What is GF-AAS?

A:

Electro thermal atomic absorption (ETAAS; GFAAS) the technique involves introducing a small amount of sample and then resistively heating a tube of graphite, which becomes the atom cell. Due to the nature of the heating mechanism the accuracy of the results are inherently increased. The tube temperature is controlled by computer input and can have a consistent temperature profile from sample to sample and from standard to sample. This element of control increases the repeatability of the method. Samples are generally entered as dilute aqueous solutions in 20-50 uL quantities.
The use of chemical modification shoud be considered if an analyte is highly volatile or if analyte and matrix volatilize at similar temperatures. The modification will allow ashing at higher (or atomization at lower) furnace temperatures, getting rid of the matrix without loosing a relatively volatile analyte (or atomizing the analyte without the matrix). Several compounds are known in the literature for this application, the most common ones are magnesium and palladium solutions. You can choose your matrix and analyte modifier from C.P.A. catalogue as well as Quality Control standard solutions for GFAAS and AAS-VGA.

Q: What is IC?

A:

Ion chromatography (IC) is a powerful technique for analysis of aqueous media containing a variety of both cations and anions. It promises to replace classical wet chemical methods for such analyses, which are frequently labor intensive and time consuming and often involve use of hazardous chemicals in the sampling protocol.

The ion chromatography is used for analysis of aqueous samples in parts-per-million (ppm) quantities of common anions (such as fluoride, chloride, nitrite, nitrate, and sulfate and common cations like lithium, sodium, ammonium, and potassium) using conductivity detectors.

Ion chromatography is a form of liquid chromatography that uses ion-exchange resins to separate atomic or molecular ions based on their interaction with the resin. Its greatest utility is for analysis of anions for which there are no other rapid analytical methods Most ion-exchange separations are done with pumps and metal columns.

Ion chromatography is the only technique that can provide quantitative analysis of anions at the ppb level. Aqueous solutions, which may require filtration, dilution, and/or cleaning to remove interferences, are required for analysis. Solid samples are extracted with water to remove ions from the sample surface. Organic liquids may also be extracted with water to obtain an aqueous solution of ions for analysis. The minimum sample required is approximately 10 mL for liquids and 2-3 square cm for solids. There are no upper limits.

C.P.A. provides mono-anions and cations solutions, and custom-made standard solution as well.

Chemical Tips and Tricks